Why exobiology on Mars?

Processing of organic molecules by liquid water was probably an essential requirement towards the emergence of terrestrial primitive life. According to Oparin's hypothesis, organic building blocks required for early life were produced from simple organic molecules formed in a primitive reducing atmosphere. Geochemists favour now a less reducing atmosphere dominated by carbon dioxide. In such an atmosphere, very few building blocks are formed. Import of extraterrestrial organic molecules may represent an alternative supply. Experimental support for such an alternative scenario is examined in comets, meteorites and micrometeorites. The early histories of Mars and Earth clearly show similarities. Liquid water was once stable on the surface of Mars attesting the presence of an atmosphere capable of decelerating C-rich micro-meteorites. Therefore, primitive life may have developed on Mars, as well. Liquid water disappeared from the surface of Mars very early, about 3.8 Ga ago. The Viking missions did not find, at the surface of the Martian soil, any organic molecules or clear-cut evidence for microbial activities such as photosynthesis, respiration or nutrition. The results can be explained referring to an active photochemistry of Martian soil driven by the high influx of solar UV. These experiments do not exclude the existence of organic molecules and fossils of micro-organisms which developed on early Mars until liquid water disappeared. Mars may store below its surface some well preserved clues of a still hypothetical primitive life.     

Application of soft computing techniques for shallow foundation reliability in geotechnical engineering

This research focuses on the application of three soft computing techniques including Minimax Probability Machine Regression(MPMR),Particle Swarm Optimization based Artificial Neural Network(ANN-PSO)and Particle Swarm Optimization based Adaptive Network Fuzzy Inference System(ANFIS-PSO)to study the shallow foundation reliability based on settlement criteria.Soil is a heterogeneous medium and the involvement of its attributes for geotechnical behaviour in soil-foundation system makes the prediction of settlement of shallow a complex engineering problem.This study explores the feasibility of soft computing techniques against the deterministic approach.The settlement of shallow foundation depends on the parametersγ(unit weight),e0(void ratio)and CC(compression index).These soil parameters are taken as input variables while the settlement of shallow foundation as output.To assess the performance of models,different performance indices i.e.RMSE,VAF,R^2,Bias Factor,MAPE,LMI,U(95),RSR,NS,RPD,etc.were used.From the analysis of results,it was found that MPMR model outperformed PSO-ANFIS and PSO-ANN.Therefore,MPMR can be used as a reliable soft computing technique for non-linear problems for settlement of shallow foundations on soils.     

Measurements in N2-CH4(C2H2) discharges of reaction rates and thermochemical constants for Titan atmosphere study

The kinetic reactions in N2-xCH4(C2H2) gas discharges with x less than 1% have been studied by emission spectroscopy in the afterglow of D.C. discharges and by mass spectroscopy from radiolysis ionization using alpha particles. The pressure range is from several Torr to 100 Torr. At the end of N2 D.C. discharges at room temperature, for a residence time of about 10(-2) s, the dominant active species are the N atoms with density of 10(14)-10(15) cm-3 for N2 density of about 10(17) cm-3 (3 Torr), the N2(X,V) vibrational molecules with for example [N2(X,V = 10)] approximately 10(14) cm-3 and the electronic metastable molecules N2(A 3 sigma u +) with a density of 10(12) cm-3. In such conditions, the following kinetic reactions have been studied: N2(A) + N2(A) --> N2(C,B,V') + N2(X), N2(A) + N2(X,V>5) --> N2(X) + N2(B,V') in pure N2 post-discharges and N2(A) + CH4 --> products, C + N + M2 --> CN(B,V') + M2, N2(X,V>4) + CN --> N2(X) + CN(B,A,V'), in N2-1% CH4 post-discharges. The clustering reactions of N2-(1-5%)CH4(C2H2) gas mixtures after radiolysis ionization have been studied for the H2CN+ nN2 ions and the equilibrium constants have been determined in the temperature range T = 140-300 K.     

Tibetan immigrants in India

"This paper documents the current evidence of the state of the Tibetan society in India with special reference to the trends in social transformation, livelihood patterns and cultural adaptation to a geographically alien environment....Three-and-a-half decades of living in India [have] demonstrated how a culture group can survive by carving out ecological niches in ethnically segregated social space and yet adapt to a new cultural environment without losing its identity."     

Thinking of England and taking care: family building strategies and infant mortality in England and Wales, 1891-1911

"Debates concerning the origins and development of the late nineteenth- to early twentieth-century declines in marital fertility and infant mortality in England and Wales have been centred largely on the material provided by answers to the ?special' questions in the 1911 census. In their published form these figures have restricted researchers to an examination of large scale geographic and social class differences in the levels and rates of decline of the two phenomena. This paper outlines research conducted on a sample of individual census returns from the 1911 census. From this data it becomes clear that for Victorian and Edwardian England ?where one lived' was rather more important than ?who one was' in determining both family building strategies and the survival of those children born."     

Results of TV imaging of Phobos (Experiment VSK-Fregat)

From February to March 1989 the Phobos 2 spacecraft took 37 TV images of Phobos at a distance of 190-1100 km. These images complement Mariner-9 and Viking data by providing higher-resolution coverage of a large region West of the crater Stickney (40-160 degrees W) and by providing disk-resolved measurements of surface brightness at a greater range of wavelengths and additional phase angles. These images have supported updated mapping and characterization of large craters and grooves, and have provided additional observations of craters' and grooves' bright rims. Variations in surface visible/near-infrared color ratio of almost a factor of 2 have been recognized; these variations appear to be associated with the ejecta of specific large impact craters. Updated determinations of satellite mass and volume allow calculation of a more accurate value of bulk density, 1.90 +/- 0.1 g cm-3. This is significantly lower than the density of meteoritic analogs to Phobos' surface, suggesting a porous interior perhaps containing interstitial ice.     

同位素地球化学、岩石地球化学——密坑山锡矿同位素年代学研究的启示

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山，火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩，火山口周围环状及放射状断裂发育，火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来，在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点，表明这一岩体对成矿具有重要的制约作用。     

Distribution and mode of occurrences of radionuclides in phosphogypsum from the Aqaba and Eshidiya fertilizer plants, Jordan

Phosphogypsum is a waste by-product of the phosphate fertilizer industry that has relatively high concentrations of some U decay-series radionuclides such as ^226Ra and ^210Pb. The distribution and environmental mobility of radionuclides in phosphogypsum are an important concern because this gypsum by-product is used for wallboard, in agriculture and as a soil amendment. This study determined the distribution of ^226Ra, ^210Pb, within phosphogypsum stacks of varying age and among three size fractions （coarse： 〈0.212 mm; medium： 0.212-0.053 mm; fine： 〈0.053 mm）, in phosphogypsum derived from Aqaba and Eshidiya fertilizer plants. The results indicated that ^226Ra and ^210Pb were generally uniformly distributed in phosphogypsum stacks and showed no significant difference in the concentration of these elements with the age of stack. In the Aqaba phosphogypsum ^226Ra was slightly 10% enriched in the coarse fraction, while ^210Pb was 10% enriched in the free size fraction. In the Eshidiya phosphogypsum ^226Ra and ^210Pb contents were both relatively enriched （10%） in the fine size fraction.     

DDT residue in soil and water in and around the abounded area of DDT manufacturing factory

Due to the persistent nature of DDT, a persistent organic pollutant and its adverse environmental and health impacts, the present study was undertaken to examine the residual DDT in and around DDT manufacturing factory in Amman Gharh, Nowshera, NWFP. The factory was established in 1963 and remained in operation till 1994. Composite samples of soil, sediments and water were collected in and around the factory area, nearby DDT stores, main factory drain leading to river and nearby villages. Standard procedures were used for the collection, transportation and storage of samples for analysis. Physical parameters for the collected water samples measured were temperature, pH and conductance. Extraction of each sample for DDT analyses was carried out in triplicates using soxhlet extraction apparatus. The extract was transferred to well washed, clean; dry glass vial, sealed and put in the refrigerator. Gas Chromatograph with electron capture detector and capillary column was used for analysis. DDT in the samples was identified on the basis of their retention time and quantified on the basis of peak areas. It is evident from the analytical data obtained in the present study that both water and soil in and around the factory area are still contaminated with DDT, despite the closure of the factory since the past few years.     

Improved reliability in the interpretation of geochemical measurements by the quantification of uncertainty from sampling

All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants （organic and metals）, previous land uses （e.g. tin mining, railway sidings and gas works）, intended future use （housing to nature reserves） and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty （〉70% of measurement uncertainty） in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation （OCLI） method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 （predicted by sampling theory）. It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment.